Abstract
The effect of specifically adsorbed halides and pseudohalides upon the kinetics of BrO 4 − electroreduction, already investigated by the authors and Cozzi [7] and, more recently, by de Levie and Nemes [8], is further examined. The inadequacy of a simple diffuse-layer correction for the kinetics of BrO 4 − electroreduction and the “direct” effect of the charge density q i at the inner Helmholtz plane ( q i-effect) upon such kinetics are stressed. An alternative method for estimating the q i-effect, based on the use of corrected Tafel plots at constant q i, is proposed.
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