Electrospun composites nanofibers from cellulose acetate/carbon black as efficient adsorbents for heavy and light machine oil from aquatic environment

Nehad A. Elmaghraby,Ahmed M. Omer,El-Refaie Kenawy,Ahmed El Nemr,Mohamed Gaber

doi:10.1007/s13738-022-02510-1

Abstract

The feasibility of preparing cellulose acetate/carbon black (CA/CB) composite nanofiber in one step through electrospinning process and investigating its potential oil absorbability and application for machine oil removal from aquatic environment was reported. Different CA/CB composite nanofibers were fabricated by electrospinning of cellulose acetate (CA) solution containing different loads of 0.7, 1.5, and 2.2% CB relative to the weight of CA and labeled as CA/CB0.7, CA/CB1.5, and CA/CB2.2. The scanning electron microscope (SEM) images showed continuous and smooth fiber with submicron diameter ranging from 400–900 nm with good adhering of CB into CA nanofiber. Furthermore, the CA/CB composite nanofibers exhibited high surface area compared with CA nanofiber, which reached 3.057, 2.8718 and 8.244 m2/g for CA/CB0.7, CA/CB1.5 and CA/CB2.2, respectively. Oil adsorption tests were performed with heavy and light machine oils. The CA/CB composite nanofibers showed higher affinity for oil removal from an aqueous solution than pure CA nanofiber. The CA/CB1.5 composite nanofiber has an exceptional performance for the adsorption of both oils, and the maximum oil adsorbed reached 10.6 and 18.3 g/g for light and heavy machine oils, respectively. The kinetic of machine oils adsorption was fitted well by the pseudo-second-order model. Besides, CA/CB composite nanofiber exposed good adsorption properties and respectable reusability after regeneration for four consecutive cycles. The results advocate the excellent potential of as-fabricated CA/CB composite nanofiber as a promising reusable oil adsorbent for oil spill cleanup applications.

Highlights

Oil pollution mainly results from offshore oil production, frequent oil spill accidents, marine transportation, petrochemical, and food industries [1,2,3]
The cleanup technique can be used to separate oil/water-free mixtures in most situations, but it has drawbacks such as poor separation performance, high energy costs, and secondary emissions [9,10,11]. The latter involves the production of smoke and dust as a result of in situ oil burning on water, as well as contamination by toxic substances as a result of the use of industrial chemical dispersants [1, 12], and they are ineffective for oil/water
The surface area of the cellulose acetate (CA) was noticed to be slightly decreased with increasing carbon black (CB) content in the composite nanofiber up to 1.5% and further increasing CB content up to with 2.2% CB

Summary

Introduction

Oil pollution mainly results from offshore oil production, frequent oil spill accidents, marine transportation, petrochemical, and food industries [1,2,3]. The cleanup technique can be used to separate oil/water-free mixtures in most situations, but it has drawbacks such as poor separation performance, high energy costs, and secondary emissions [9,10,11]. The latter involves the production of smoke and dust as a result of in situ oil burning on water, as well as contamination by toxic substances as a result of the use of industrial chemical dispersants [1, 12], and they are ineffective for oil/water

Methods

Findings

Discussion

Conclusion