Abstract
In this study, we report on the fabrication and utilization of NiCr alloy nanoparticles (NPs)-decorated carbon nanofibers (CNFs) as efficient and competent non-precious catalysts for the hydrolytic dehydrogenation of ammonia borane (AB) at 25 ± 2 °C. The introduced NFs have been fabricated in one step using a high-temperature thermal decomposition of the prepared electrospun nanofiber mats (nickel acetate tetrahydrate, chromium acetate dimer, and polyvinyl alcohol) in an inert atmosphere. The chemical composition of the NFs with different proportions of Ni1−xCrx (x = 0.0, 0.1, 0.15, 0.2, 0.25, 0.3) was established via standard characterization techniques. These techniques proved the formation of disorder Cr2Ni3 alloy and carbon for all the formulations. The as-synthesized composite NFs exhibited a higher catalytic performance for AB dehydrogenation than that of Cr-free Ni–CNFs. Among all the formulations, the sample composed of 15% Cr shows the best catalytic performance, as more H2 was released in less time. Furthermore, it shows good stability, as it is recyclable with little decline in the catalytic activity after six cycles. It also demonstrates the activation energy, entropy (ΔS), and enthalpy (ΔH) with 37.6 kJ/mole, 0.094 kJ/mole, and 35.03 kJ/mole, respectively. Accordingly, the introduced catalyst has a lower price with higher performance encouraging a practical sustainable H2 energy application from the chemical hydrogen storage materials.
Highlights
The fast growth of the global population associated with social development and technologies requires a sufficient and sustainable energy supply
Our previous works exhibit that carbon nanofibers (CNFs) can assist with dispersing and stabilizing the transition metal NPs, and can be used for various applications [25,38]
The final solutions were stirred at 60 ◦C for 6 h, and cooled at room temperature for obtaining a clear sol–gel
Summary
The fast growth of the global population associated with social development and technologies requires a sufficient and sustainable energy supply. Ni NPs tend to oxidize in air or aqueous solution; they aggregate and fuse, owing to their magnetic-induced property and increased surface energy [9,19,22] These issues not merely limit their catalytic activity level; they sharply reduce the recycling performance. Our previous works exhibit that CNFs can assist with dispersing and stabilizing the transition metal NPs, and can be used for various applications (e.g., fuel cells and hydrogen production) [25,38]. Another strategy is the addition of an atomic diffusion barrier (e.g., Cr, Mo, and W) to Ni atoms [39].
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