Electroreductive alkylation of iron porphyrins. Iron(III), iron(II) and iron(I) alkyl complexes from the reaction of doubly reduced iron(II) porphyrins with alkyl halides

Doris Lexa,Jean Michel Saveant,Dan Li Wang

doi:10.1021/om00138a022

Electroreductive alkylation of iron porphyrins. Iron(III), iron(II) and iron(I) alkyl complexes from the reaction of doubly reduced iron(II) porphyrins with alkyl halides

Doris Lexa, Jean Michel Saveant + Show 1 more

https://doi.org/10.1021/om00138a022

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Journal: Organometallics	Publication Date: Jul 1, 1986
Citations: 56

#Iron Porphyrins #Alkyl Complexes + Show 3 more

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Abstract

L'etude electrochimique de la reduction de quatre porphyrines de fer (octaethylporphyrine, tetraphenylporphyrine, basket-handle porphyrines) en presence d'halogenures d'alkyle montre que non seulement le complexe de fer(II) est reduit en complexe de fer(I) mais il se produit une alkylation a l'atome de fer

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