Abstract
A major advantage of organic solar cells (OSC) is the processability out of solution allowing for advanced printing methods toward large-scale production. Controlling the blend morphology of solution coated active layers is a key challenge to optimize their power conversion efficiency. We have derived a printing procedure from an industrial coating process that facilitates tuning the nanomorphology of a blend of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) as model system for OSCs. Applying an electric field during printing and the film drying process modifies the vertical film composition of the photoactive layer and optimizes the polymer crystal orientation. The choice of chloroform as solvent allows us to obtain material transport within the wet film, due to an induced electrophoretic mobility. Tailoring the morphology improves the power conversion efficiency of the OSCs by up to 25%. Our findings indicate that electrophoresis assisted printing provides an efficient approach to optimize the active layer for various material and solvent combinations that exhibit an electrophoretic mobility.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
