Abstract

1. The rate of the reaction of phenylmercury bromide with HCl in aqueous dioxane is inhibited by the mercuric chlorobromide formed. 2. The kinetics of protolysis was studied in the presence of sodium iodide in 90% aqueous dioxane. From the temperature dependence of the reaction, the parameters of the Arrhenius equation were found. 3. The catalytic effect of NaI is very great and is explained by interaction of NaI with phenylmercury bromide, forming a complex. The reaction rate is a linear function of the concentration of the complex.

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