Abstract

Arylpolynitromethanes, the products of the electrochemical oxidation of polynitrocarbanions in the presence of benzene and its substitution products, are formed by homolytic aromatic substitution. During this process the intermediate polynitroalkyl radicals show electrophilic properties. The yield of arylpolynitromethanes depends on radical structure and on the electron donor properties of the aromatic substrate.

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