Abstract
The literature data on the electrophilic heterocyclization reactions of unsaturated amines, enamines, amidines, amides, and urethanes are correlated. The factors that affect the reactivities of unsaturated amino compounds in electrophilic intramolecular-cyclization reactions are discussed. The problems involved in the regioselectivity of the addition of electrophiles and the stereochemistry of the resulting products are examined, and kinetic data are presented.
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