Abstract

Regioselective anodic fluorination of cyclic ethers, lactones, and a cyclic carbonate in Et 4NF· nHF ( n=4, 5) and Et 3N·5HF without a solvent was successfully carried out to give the corresponding monofluorinated products in moderate yields. This is the first report of direct electrochemical fluorination of cyclic ethers, lactones, and a cyclic carbonate using anodic fluorination.

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