Electronic tuneability of a structurally rigid surface intermetallic and Kondo lattice:CePt5/Pt(111)

Abstract

We present an extensive study of the structure, composition, electronic, and magnetic properties of Ce-Pt surface intermetallic phases on Pt(111) as a function of their thickness. The sequence of structural phases appearing in low-energy electron diffraction may invariably be attributed to a single underlying intermetallic atomic lattice. Findings from both microscopic and spectroscopic methods prove compatible with ${\mathrm{CePt}}_{5}$ formation when their characteristic probing depth is adequately taken into account. The intermetallic film thickness serves as an effective tuning parameter which brings about characteristic variations of the cerium valence and related properties. Soft x-ray absorption (XAS) and magnetic circular dichroism (XMCD) prove well suited to trace the changing Ce valence and to assess relevant aspects of Kondo physics in the ${\mathrm{CePt}}_{5}$ surface intermetallic. We find characteristic Kondo scales of the order of ${10}^{2}$ K and evidence for considerable magnetic Kondo screening of the local Ce $4f$ moments. ${\mathrm{CePt}}_{5}/\mathrm{Pt}(111)$ and related systems therefore appear to be promising candidates for further studies of low-dimensional Kondo lattices at surfaces.