Electronic structures of organometallic complexes of f elements LXXIII: Parametric analysis of the crystal field splitting pattern of tris(η 5-pentamethylcyclopentadienyl)cerium(III)

Abstract

By comparing the far infrared (polyethylene pellets, room temperature) and mid-infrared spectra (KBr pellets, room temperature and ca. 90 K) of pseudo trigonal planar Ce(η 5-C 5Me 5) 3 ( 1) with the corresponding ones of La(η 5-C 5Me 5) 3 ( 2) and considering the low temperature paramagnetic susceptibility data of 1 the crystal field (CF) splitting pattern of 1 could be derived. The free parameters of a phenomenological Hamiltonian were fitted to this pattern achieving an r.m.s. deviation of 8.9 cm −1 for seven assignments. The fact that the difference of the experimental energies of the barycenters of CF levels of the multiplets 2F 7/2 and 2F 5/2 is larger than in the gaseous free Ce 3+ ion (experimental “anti”-relativistic nephelauxetic effect) could be explained by coupling effects of these multiplets via the CF, resulting in a lower spin–orbit coupling parameter than in the case of the free gaseous Ce 3+ ion. The experimental CF splitting pattern of 1 is compared to the results of a relativistic DV-Xα calculation on the pseudo trigonal planar model compound Ce(η 5-C 5H 5) 3. In addition, the prediction of the energies of f → d and charge transfer transitions of Ce(η 5-C 5H 5) 3 are compared to the absorption and luminescence spectra of complex 1.