Electronic structure, thermodynamic stability and high-temperature sensing properties of Er-\u03b1-SiAlON ceramics

Yuwaraj K Kshetri,Tae-Ho Kim,Sang Hoon Jeong,Jun Zhou,Soo Wohn Lee,Heechae Choi,Yuan Ping Feng,Takashi Kamiyama,Shuki Torii

doi:10.1038/s41598-020-61105-z

Abstract

α-SiAlON ceramics have been in use as engineering ceramics in the most arduous industrial environments such as molten metal handling, cutting tools, gas turbine engines, extrusion molds, thermocouple sheaths, protective cover for high-temperature sensors, etc., owing to their outstanding mechanical, thermal and chemical stability. Taking advantage of the intrinsic properties of α-SiAlONs, we investigate, in this paper, the possibility of using the Er-doped α-SiAlON (Er-α-SiAlON) ceramic as a high-temperature sensing material via its unique near-infrared to visible upconversion property. We first use neutron diffraction and density functional theory calculations to study the electronic structure and thermodynamic stability of Er-α-SiAlON. It is found that the interstitial doping of Er stabilizes the α-SiAlON structure via chemical bonds with O-atoms with N:O ratio of 5:2 in the seven-fold coordination sites of the Er3+ ion. Temperature-dependent upconversion emissions are then studied under 980 and 793 nm excitations over a temperature range of 298–1373 K and the fluorescence intensity ratio (FIR) technique has been employed to investigate the temperature sensing behavior. Temperature-dependent Raman behavior is also investigated. We demonstrate that using Er-α-SiAlON as a sensing material, the limit of temperature measurement via the FIR technique can be pushed well beyond 1200 K.

Highlights

SiAlON ceramics are high-performance refractory ceramics which are manufactured by combining raw materials silicon nitride, alumina, aluminum nitride along with the oxide of rare earth elements
Er-α-SiAlON ceramic has a maximum sensitivity of 3.4 × 10−3 K−1 at 448 K and a relative sensitivity of 0.59% K−1 under 793 nm www.nature.com/scientificreports excitation
Our results show that using Er-α-SiAlON ceramics as the sensing material, the limit of the temperature measurement via optical thermometry can be pushed beyond 1200 K, the highest temperature measurement via the fluorescence intensity ratio (FIR) technique

Summary

Introduction

SiAlON ceramics are high-performance refractory ceramics which are manufactured by combining raw materials silicon nitride, alumina, aluminum nitride along with the oxide of rare earth elements. Α-SiAlON ceramics are widely used for high-temperature and high-endurance applications owing to their ability to withstand high structural loads and their excellent thermal and chemical stability[4,5] Taking advantage of their superior mechanical, thermal and chemical stabilities, these materials have been investigated recently for the possibility of functional applications such as downshifting phosphor materials for solid-state lighting[6]. Tellurite glass-based material cannot be used for temperature above 250 °C (523 K) due to its very low transition temperature (350 °C) To overcome these limitations, Er-α-SiAlON ceramic can be a potential candidate for the optical thermometry applications based on the FIR technique. A particular advantage of investigating the Er-α-Sialon as a high-temperature sensor material is that it has outstanding mechanical, thermal and chemical stability even at an elevated temperature above 1000 °C (1273 K)[4]. We investigate the temperature dependence of the Raman spectra of Er-α-SiAlON which has not been reported for SiAlON-based materials

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Discussion

Conclusion