Abstract
We study the electronic structure of copper oxide clusters, ${\mathrm{Cu}}_{2}$${\mathrm{O}}_{\mathit{x}}$ (x=1\char21{}4), using anion photoelectron spectroscopy and density-functional calculations. The experiment is used to successfully guide a computational search for the cluster geometries. The predicted electron affinities at the obtained cluster structures reproduce exactly the trend observed experimentally. The definitive determination of the cluster structures enables a detailed analysis of the chemical bonding and electronic structure involving Cu atoms in different oxidation states exhibited by these clusters. \textcopyright{} 1996 The American Physical Society.
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