Abstract
Angular resolved photoemission spectra using synchrotron radiation have been measured for different amounts of cobalt evaporated on Cu(100). At room temperature cobalt grows layer-bylayer forming well-ordered layers in registry with the substrate, as judged by AES, LEED and UPS measurements. The energy position and linewidth of the Cu peaks remain unchanged when cobalt is deposited onto the surface, suggesting a rather weak interaction between the d-bands of Co and Cu. The two-dimensional band structure of the monolayer of cobalt has been determined. We have obtained a value for the magnetic exchange splitting of ΔE exch = 0.80 ± 0.15 eV, which is nearly identical to the bulk value. A shift in the energy positions of the critical points for the monolayer versus bulk of cobalt is interpreted in terms of a narrower 2D density of states in the monolayer as compared to the bulk. A resonant valence-band two-electron satellite has been found. The correlation energy and screening effects of the two d-holes are very similar to the corresponding bulk values, while the decreased intensity of the satellite at resonance compared to the one for Co(0001) suggests that there are more d-states relative to s-states in the monolayer than in a bulk cobalt single crystal, in agreement with recent models of the valence band electronic structure at surfaces.
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