Abstract
The structure of 10-alkyl(aryl)phenoxarsines has been investigated by the semiempirical quantum-chemical PM3 method. The AsIII atom has a positive charge and simultaneously exhibits nucleophilic properties in the reaction with methyl, iodide. The reactions of 10-alkyl(aryl)phenoxarsines with methyl iodide are probably controlled by charge distribution.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR, Division of chemical science
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