Abstract
Studying the modulation of nanoclusters at an atomic scale is essential to comprehend the connection between properties and catalytic performance. Herein, we synthesized and characterized Pdn (n = 2-5) nanoclusters coordinated with di-1-adamantylphosphine. Pd5 nanoclusters showed the best catalytic performance (conversion = 99.3%, selectivity = 95.3%) for the hydrogenation of cinnamaldehyde to hydrocinnamaldehyde, with XPS identifying Pdδ+ as the key active component. This work aimed to explore the relationship among the number of Pd atoms, their electronic structure and catalytic activity.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.