Abstract
Cr 2 is produced by pulsed YAG laser vaporization of chromium metal and its fluorescence excitation spectrum is analyzed. The high value of vibrational frequency Δ G″ 1 2 = 452.34 cm −I (ω″ e ≈ 470 cm −1) and short internuclear distance r″ e = 1.6788 Å are indicative of a very strongly bound 1∑ + g ground state.
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