Abstract
Electronic absorption and magnetic circular dichroism (MCD) spectra in the UV-visible region are reported for acetonitrile solutions of [M(dto) 2 ](ClO 4 ) 2 , dto=3,6-dithiaoctane, M=Pt(II) and Pd(II); [(n-C 4 H 9 ) 4 N] 2 °M(SCN) 4 ] M=Pt(II) and Pd(II); and M(Et-Xan) 2 , Et-Xan - =ethyl xanthate, M= Pt(II), Pd(II), and Ni(II). The intense bands and the MCD B terms observed for the Pd(II) and Ni(II) complexes are generally assigned to ligand to metal charge transfer (LMCT) from orbitals of the S donor to the empty metal dσ * orbital (nd x2-y2 )
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