Abstract

We have studied the electronic structure within the topmost two quintuple layers (QL) on vacuum-cleaved n- and p-type Bi2Te3(111) at 10 K by angle-resolved photoelectron spectroscopy. Tunable synchrotron radiation maximized the surface sensitivity of photoelectrons. The gapless surface-state band (SSB) in the angle-resolved photoelectron spectra clearly demonstrates the topological nature of the samples. Below the SSB, the bulk valence bands (BVB) is observed. Against the three-fold symmetry of the crystal structure, the k|| dispersion of the BVB is highly symmetrical around the Γ, which indicates the six-fold symmetry. Moreover, most of the BVB show almost flat k⊥ dispersion perpendicular to the surface. These facts are the experimental evidence of a strong modification of the valence bands within the topmost two QLs into highly two-dimensional states by the advent of the surface. [DOI: 10.1380/ejssnt.2012.117]

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