Abstract

The chapter outlines arrays of the valence, ion-pair (IP) and Rydberg states of the iodine molecule. At the outset, a molecular orbital theory used for descriptions of the valence and IP states, pure precession model utilized for the IP states, and the describing of the Rydberg states are defined. Then, the valence states and valence-valence transitions, as well as the IP states and IP – valence transitions are described in details. Data given in this Chapter will be used for descriptions of intra- and intermolecular perturbation described in Chaps. 4, 5 and 6.

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