Abstract
The S1←S0 fluorescence excitation spectra of jet-cooled tropolone (TRN)–Mn (M=Ar, Kr, Xe, N2, CH4/CD4, C2H6, C3H8, CCl4; n=1,2) clusters have been measured in the wavelength region near the electronic origin to investigate the effects of van der Waals interactions on proton tunneling in the electronic excited S1 state. The solvation of TRN with the rare gas atom(s) has small effect on the 000 tunneling splitting, while the solvation with the molecule(s) considerably decreases the tunneling splitting. The decrease in the tunneling splittings of the TRN clusters has been explained by strong coupling of intermolecular vibration with intramolecular vibration of TRN, increasing the effective potential barrier height and/or tunneling distance. The anisotropy in the intermolecular interactions, and the configuration and number of solvent molecules are suggested to be important factors for the changes in the tunneling splitting.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
