Abstract
Cs x C 60 compounds were prepared by the reaction of C 60 films with Cs vapor and investigated by means of photoemission spectroscopy. Samples of the whole range of stoichiometry 0⩽ x⩽6 were characterized. Upon doping the lowest unoccupied molecular orbital of C 60 which is derived from the t 1u orbital becomes filled, but the material does not show metallic properties at any composition indicating that correlation effects remain significant in the doped compound. The diffusion of Cs into the closely packed fcc lattice of weakly doped C 60 is very slow at room temperature. It becomes much faster after the phase transition to the more open bct and bcc structures.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
