Electronic energy pooling in organic systems: a cross-disciplinary tutorial review

Abstract

Electronic energy pooling via excited state (exciton) annihilation, primarily in organic systems, is reviewed in tutorial form. Cross-disciplinary terminologies and references are used and reference is made to the historical origins of the phenomena. Applications in organic photovoltaic and electroluminescent devices are addressed. Particular attention is paid to the kinetics of the processes involved; a standard format for all systems is developed. Within the organic materials framework, all triplet–triplet, triplet–singlet, and singlet–singlet annihilation processes are discussed. Examples from gas, liquid, and solid phase systems, including both homo- and hetero-species interactions, are employed. Particular attention is given to triplet–triplet annihilation processes in which product states other than the lowest excited singlet state are formed.