Abstract
Owing to numerous new applications, the interest in "task-specific" ionic liquids increased significantly over the last decade. But, unfortunately, the imidazolium-based ionic liquids (by far the most frequently used cations) have serious limitations when it comes to modifications of their properties. The new generation of ionic liquids, called tunable aryl-alkyl ionic liquids (TAAILs), replaces one of the two alkyl chains on the imidazolium ring with an aryl ring which allows a large degree of functionalization. Inductive, mesomeric, and steric effects as well as potentially also π-π and π-π(+) interactions provide a wide range of possibilities to tune this new class of ILs. We investigated the influence of electron-withdrawing and -donating substituents at the para-position of the aryl ring (NO(2), Cl, Br, EtO(CO), H, Me, OEt, OMe) by studying the changes in the melting points of the corresponding bromide and bis(trifluoromethanesulfonyl)imide, (N(Tf)(2)(-)), salts. In addition, we calculated (B3LYP/6-311++G(d,p)) the different charge distributions of substituted 1-aryl-3-propyl-imidazolium cations to understand the experimentally observed effects. The results indicated that the presence of electron-donating and -withdrawing groups leads to strong polarization effects in the cations.
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