Abstract
The oxidation of olefins (alicyclic compounds and stilbenes) by permanganate ion is accelerated by electron-attracting substituents, but these groups retard the reactions of the olefins with osmium tetroxide. For the stibene oxidations, approximate ρ values obtained were: 0·65 for the permanganate reactions in aqueous dioxan and –0·55 for the osmium tetroxide reactions in dioxan.
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