Electronic conductivity of vanadium-tellurite glass-ceramics

Abstract

In this paper, we investigate the electronic conductivity of 2TeO2–V2O5 glass-ceramics with crystallinity ranging from 0 to 100wt.%, i.e., from entirely amorphous to completely crystalline. The glass is prepared by the melt quenching technique, and the crystal is prepared by subsequent heat treatment thereof. Glass-ceramics are prepared by mixing glass and crystal powder, followed by a sintering procedure. Activation energies for electronic conduction in the glass and in the crystal are determined by fitting the Mott–Austin equation to the electronic conductivity data obtained by impedance spectroscopy. We find similar activation energies for both glass and crystal, implying that they have similar conduction mechanisms, i.e., thermally activated hopping. The electronic conductivity of 2TeO2–V2O5 glass is about one order of magnitude higher than that of the corresponding crystal, and a percolation phenomenon occurs at a glass fraction of 61wt.%, increasing from a lower conductivity in the crystal to a higher conductivity in the glass. We explain the behavior of electronic conduction in the 2TeO2–V2O5 glass-ceramics by considering constriction effects between particles as well as percolation theory. This work implies that, based on its electronic conductivity, vitreous 2TeO2–V2O5 is more suitable as a cathode material in secondary batteries compared to a 2TeO2–V2O5 glass-ceramic.