Abstract
Electronic absorption spectra of C7O, neutral and cationic, have been obtained after mass selection and deposition into 6 K neon matrices. The band system with origin at 305.1 nm is identified as the (2) 1Σ+ ← X 1Σ+ electronic transition of linear C7O, and the absorption, with onset at 276.0 nm, to (4) 2Σ+ ← X 2Σ+ of C7O+ on the basis of experimental observations and theoretical calculations.
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