Abstract
Computational evidence is reported for a reversal in the type of an electron transfer (ET) mechanism, induced by an intramolecular linkage of the donor (amine) and acceptor (cation radical) moieties via a single –CH2– spacer. An isotope effect probe is suggested to detect this mechanistic changeover.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have