Electron transfer and exciplex chemistry of functionalized nanocarbons: effects of electronic coupling and donor dimerization.

Abstract

In the past few decades, research on the construction of donor-bridge-acceptor linked systems capable of efficient photoinduced charge separation has fundamentally contributed to the fields of artificial photosynthesis and solar energy conversion. Specifically, the above systems are often fabricated by using carbon-based nanomaterials such as fullerenes, carbon nanotubes, and graphenes, offering limitless possibilities of tuning their optical and electronic properties. Accordingly, since understanding the structure-photodynamics relationships of π-aromatic donor-bridge-nanocarbon linked systems is crucial for extracting the full potential of nanocarbon materials, this review summarizes recent research on their photophysical properties featuring nanocarbon materials as electron acceptors. In particular, we highlight the electronic coupling effects on the photodynamics of donor-bridge-nanocarbon acceptor linked systems, together with the effects of donor dimerization. On a basis of their time-resolved spectroscopic data, the photodynamics of donor-bridge-nanocarbon acceptor linked systems is shown to be substantially influenced by the formation and decay of an exciplex state, i.e., an excited-state consisting of a π-molecular donor and a nanocarbon acceptor with partial charge-transfer character. Such basic information is essential for realizing future application of carbon-based nanomaterials in optoelectronic and energy conversion devices.