Abstract
Synthetic methane hydrate irradiated by γ-rays at 77 K has been measured by electron spin resonance (ESR). The quartet signal at g=2.0029±0.0005 with the intensity ratio of approximately 1:3:3:1 and hyperfine coupling constant A=2.3±0.1 mT was identified as the methyl radical (CH3·). The dose response of its signal intensities showed that the radicals were formed linearly up to 10 kGy with the G-value [the formation efficiency of radical pairs per 100 eV (16 aJ)] of 0.05. According to annealing experiments, the radical became unstable over 200 K, at which thermal dissociation of the hydrate had already started, but a very weak signal was detectable up to 270 K. The methyl radical thermally decayed following second-order kinetics with an activation energy of 0.26±0.02 eV (42 zJ). The existence of the signal at 270 K would be related to the extremely slow dissociation referred to as the self-preservation effect of the gas hydrate.
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