Abstract
The e.s.r. spectra of o-benzosemiquinone alkali metal ion pairs have been recorded over a large range of temperature and for several solvents. The hyperfine coupling constants of the metal nuclei and their variation with temperature are discussed in relation to theoretical calculations performed for different models of the ion pairs. 13C splittings are measured for carbon nuclei occurring in the three different positions in the molecule in natural isotopic abundance and their assignment is discussed. Spectra due to other radical species are observed and are attributed to substituted quinones.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society, Faraday Transactions 2
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
