Abstract
The adsorption and/or decomposition pathway of Fe2(CO)9 or Fe3(CO)12 on hydrated or dehydrated NaY zeolites has been studied by an ESR technique. The adsorption resulted in the formation of three paramagnetic species withgiso=2.0450, 2.0378, and 2.0016, which were attributable to Fe3(CO)11−, Fe2(CO)8−, and Fe(CO)4− anion radicals, respectively. These radicals have been suggested as intermediates in the formation of HFe3(CO)11− on the hydrated NaY zeolite and Fe3(CO)12 on the dehydrated NaY zeolite.
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