Abstract
Suggestions for the mechanism of electron solvation in methanol during the last three decades were mostly based on limited time resolution measurements, or indirect observations. The two-channel solvation scheme proposed by Lewis and Jonah (1986) based on indirect observations in electron scavenging experiments is checked here to see if it is in accordance with recent sub-picosecond pump-and-probe laser experimental results. We confirm the applicability of this solvation mechanism and calculate quantitative kinetic and spectral parameters involved.
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