Abstract
The EPR spectroscopic properties of the zero-valent rhodium complex [Rh(P(OPr i ) 3) 4] have been examined at both X- and Q-band frequencies. The spectra show a large, essentially axial anisotropy and ligand hyperfine coupling to four equivalent 31P phosphorous nuclei. No resolved coupling to 103Rh was detected. The data indicate a tetragonally compressed tetrahedral structure (D 2d) rather than the alternative C 3v geometry provisionally proposed for the related [Co(P(OMe) 3) 4] complex.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
