Abstract

The electron mobility and the free ion yield in liquid and solid cyclohexane have been measured as a function of temperature using X-ray pulse radiolysis. The zero-field free ion yield decreases with decreasing temperature in both liquid and solid, and exhibits a discontinuous decrease on the phase change from liquid to solid. The electron mobility in liquid from room temperature to the freezing point decreases and approaches to that in solid cyclohexane which also decreases with decreasing temperature. The observed values of the electron mobility and the zero-field free ion yield just below the freezing point are 0.07 cm 2/V· s and 0.05, respectively.

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