Abstract

Molecular composites are a new class of structural polymers which are lightweight, high-strength, high-modulus, and environmentally resistant. A rigid-rod, extended chain, polymer is used to reinforce a matrix of flexible, coil-like polymer with the intent of achieving a composite on the molecular level which is analagous to a macroscopic chopped-fiber reinforced composite. The critical factor in making a molecular composite is that the rod-like reinforcing molecules be well dispersed and not phase separate from the matrix polymer to insure that the aspect ratio (ratio of length to width) of the reinforcing phase has a high value. This paper reports the first transmission electron microsopy (TEM) study of phase separation in molecular composites.

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