Abstract
AbstractA series of 2‐chlorovinyl methyl sulphides, CH3SCR1CR2Cl (R1, R2 = H, Me, Et, t‐Bu, Ph; R1 = H, R2 = CH3) has been analysed under electron impact conditions. The most significant common fragmentations involve primary loss of Cl˙ and methyl radicals. Analysis of the phenyl‐substituted derivative suggests that loss of CH3˙ is a lower activation energy process than loss of Cl˙. The characteristic loss of CH3SCl from the same derivative has been examined with respect to the structure of the resulting fragment by means of suitable model compounds.
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