Electron impact cross sections of vibrationally and electronically excited molecules

Abstract

It is well known that the electron impact cross sections for elastic and inelastic processes for the vibrationally and electronically excited molecules are predominantly different than those for molecules in the ground state. Collisions of low energy electrons with excited molecules play an important role in explaining the behavior of gas discharges in laser and plasma physics, in planetary atmospheres, stars, and interstellar medium and in plasmas widely used in the fabrication of microelectronics. This explains as to why there is a need for having validated sets of electron impact cross sections for different processes. This work reviews the subject of electron collisions with vibrationally and electronically excited molecules in a comprehensive way. The survey has been carried out for a few excited molecules such as H2, D2, T2, HD, HT, DT, N2, O2, and CO2.This review includes the discussion on the methods to produce and detect vibrationally and electronically excited molecules. We will take up the cross section data available in the literature for such molecules on electron scattering, dissociation, ionization and attachment processes and will discuss, evaluate and well-validate the same wherever and whenever possible.