Abstract

A new experimental method has been developed for measurements of the rate constants of electron attachment as a function of the mean electron energy. The conventional pulse-radiolysis microwave-cavity method has been modified by applying the microwave heating technique to elevate the mean electron energy from thermal to about 1 eV. This technique has been applied to the electron attachment to c-C 7F 14, CH 3I and CH 2Br 2 in Xe buffer gas. The results are discussed in comparison with existing data.

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