Abstract
Electron-deficient tin(IV)tetraphenylporphyrin perchlorate, [Sn IV(TPP)(ClO 4) 2] was used as a highly efficient catalyst for chemical fixation of carbon dioxide. The bifunctional catalytic system [Sn(TPP)(ClO 4) 2]/tetrabutylphosphonium bromide (TBPB) was applied for preparation of cyclic carbonates from epoxides and carbon dioxide. The effect of reaction parameters was also investigated.
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