Abstract

The ECC cusp shapes for bare H and He projectiles on hydrocarbon (C m H n ) gas targets show an abrupt, small change when m ⩾ 4. Similar shape changes were sought in the ECC cusps obtained with bare H and He projectiles on the fluorocarbon gas series, CF 4, C 2F 6 and C 2F 8. Analyses of these spectra indicate little shape change among the fluorocarbon sequence. The ramifications of this result for the possibility of “wakes” in molecules will be discussed.

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