Abstract
Thermal radiolysis under the conditions of electron-beam distillation at a dose to 240 kGy converts petroleum sludge into C4–C31 hydrocarbons with a yield to 80 wt %. The condensate distilled off contains about 20 wt % alkenes, thereby indicating the chain regeneration and thermal fragmentation of bulky alkyl radicals. The yield of the condensate increases to 90 wt % in the case of mixing the initial petroleum sludge with lignin. In this case, the yield of alkenes is lower due to the binding of unsaturated compounds by the components of charcoal and tar and because of a change in the mechanism of alkane fragmentation in the presence of lignin.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.