Abstract
The electromigration behaviour of carrier-free241Am−Am(III) in inert electrolytes, μ=0.1 (C10 4 − ), T=298.1(1) K, was studied. On the basis of the overall ion mobilities of241Am−Am(III) on pH between pH 5.5 and 12.9, the stoichiometric hydrolysis constants p 3 β3 =23.8(9), and pK1=6.9(2) were obtained. For K4 a limitation of pK4≧14.4(3) was possible, because no formation of anionic hydrolysis products in solutions pH≦12.9 was registered. The individual ion mobility of the241Am−Am3+ decrease in the range pH 5.5–3 from +6.85(15) up to +5.50(15)·10−4 cm2·s−1·V−1. Dependences of this effect on overall ionic strength, inert electrolyte anion, and the temperature of the electrolytes were studied in acidic and neutral solutions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Radioanalytical and Nuclear Chemistry Articles
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
