Abstract
Stoichiometric stability constants of the thallium (I) sulphate complex [Tl(SO4)]− have been determined by measurements of the 201Tl.Tl(I) ion mobility at 298.1 (1) K in solutions of Na2SO4/Na(H)ClO4, μ = 0.1, pH ≦ 4, and Na2SO4/H2SO4, 0.1 ≦ μ ≦ 0.48, pH 2–2.5. The thermodynamic stability constant of this complex anion of = 15.7(1.0) 1 · mol−1 has been calculated on the basis of experimental data.
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