Electromechanical properties and photoluminescence of Er3+-doped PMN-33PT single crystal

Abstract

Based on the successful growth of large-sized Er3+-doped PMN-PT single crystal, the phase composition, electromechanical properties and photoluminescence of [001]C-oriented Er3+-doped PMN-33PT crystal were investigated in detail. The results show that the crystal coexists in rhombohedral and monoclinic phases at room temperature. The crystal possesses excellent piezoelectric (d33 ∼ 2103 pC/N), dielectric (ε33T ∼ 7589), and electromechanical coupling properties (k33 ∼ 0.91), accompanied by a higher phase transition temperature and larger coercive field compared with that of PMN-33PT single crystal. This indicates an improved electromechanical performance induced by Er3+ doping. Additionally, the crystal achieves upconversion and downconversion luminescence, and a strong dependence of the upconversion emission on temperature is demonstrated. Furthermore, a comparable optical temperature sensing performance based on the fluorescence intensity ratio of the upconversion luminescence is verified. These results demonstrate a promising multifunctional material. The electro-optical coupling performance of the Er3+-doped PMN-33PT crystal is under evaluation.