Abstract

It is shown that a frame of reference—solvent provides a chance to determine only the overall electromasstransfer, whereas employing a frame of reference—solution allows one to separately measure parameters of electrotransfer and mass transfer. A mechanism of formation of stable ionic boundaries in electrolytic solutions upon passing a constant electric current is discussed. A technique for the determination of velocities of solutions moving to and from an ionic boundary under the action of a pressure gradient emerging in the vicinity of the boundary is proposed.

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