Electromagnetic and microwave absorption properties of flexible fabric coatings containing Ag decorated spherical graphene powders with FSS incorporation

Abstract

Flexible textile microwave absorbing materials own the advantages of flexibility, foldability and cuttability, have become a research hotspot in electromagnetic stealth technology. In this study, a microwave absorbing coating was prepared on a fabric substrate using Ag decorated spherical graphene (SG) as the absorbent. XRD results demonstrated the metallic Ag ion was successfully reduced. TEM photographs showed the silver nanoparticles were stuck to the spherical graphene. The complex permittivity was enhanced after compositing with Ag particles. Along with the increase of silver content from 0 to 20 wt%, the complex permittivity rises from 3.29–0.42j to 6.93–2.22j owing to its higher electric conductivity and stronger relaxation effect. Meanwhile, the flexible coating containing Ag decorated spherical graphene (Ag@SG) also exhibited better microwave absorption performance. The minimum reflection loss (RLmin) for the coating with a thickness of 3.0 mm was −15 dB. And the effectively absorbing broadband (EAB) is located at 9.08–11.52 GHz. In addition, the microwave absorbing performance was greatly enhanced after being combined with periodic frequency selective surface (FSS). The EAB was obtained over the entire X-band frequency range, and the RLmin value achieved −41.72 dB at 10.25 GHz. What's more, the coating owned an EAB in a wide range incident angle of 60°–90°. This work was help to developing high performance flexible fabric coating containing Ag decorated spherical graphene with FSS incorporation.