Abstract
The electrolytic separation factor, α, has been measured for 17O and 18O at Pt and Ni anodes in both light and heavy water solutions of as a function of current density. For oxygen‐17, isotopic separation effects were not observed, within the experimental uncertainty of ±2%, under all conditions studied. For oxygen‐18, three is a small difference of 2% in α values between Pt and Ni in both light and heavy water solutions, but there is no significant difference in α values between light and heavy water solutions. In light water solutions, the separation factor at Pt is small, for . This value agrees reasonably well with theoretical estimates.
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