Electrolytes for High-Safety Lithium-Ion Batteries at Low Temperature: A Review.

Abstract

As the core of modern energy technology, lithium-ion batteries (LIBs) have been widely integrated into many key areas, especially in the automotive industry, particularly represented by electric vehicles (EVs). The spread of LIBs has contributed to the sustainable development of societies, especially in the promotion of green transportation. However, the high demand for battery performance and safety in these fields has made the high viscosity, volatility, and potential leakage inherent in traditional organic liquid electrolytes a constraint on their further expansion. Especially at low temperature, the increased viscosity of the electrolyte, reduced solubility of lithium salts, crystallization or solidification of the electrolyte, increased resistance to charge transfer due to interfacial by-products, and short-circuiting due to the growth of anode lithium dendrites all affect the performance and safety of LIBs. Therefore, improving the safety performance of LIBs under low-temperature environments has become a focus of current research. This paper primarily reviews the progress made in utilizing different types of electrolytes in LIBs to enhance safety and optimize low temperature performance and discusses the current research progress as well as the future development direction of the field.