Abstract
The electrochemical decomposition of free and vanadyl tetraphenyl porphyrin in xylene solutions, and in the presence of water, using K2SO4 as electrolyte, was studied. Electrolysis of the two-phase system was carried out at constant current density and potential. It was observed that the electrochemical decomposition of the porphyrins, using a two-phase liquid system, is possible. An inexpensive organic solvent (xylene instead of THF, acetonitrile, methylene chloride etc.) can be very effectively used in such a system. The decomposition occurs through an oxidation process, with the subsequent formation of cationic and dicationic radicals, and a final breakdown of the macrocycle.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.